Spatial patterns of groundwater‐lake exchange – implications for acid neutralization processes in an acid mine lake     

Christiane Neumann  Julia Beer  Christian Blodau  Stefan Peiffer  Jan H. Fleckenstein 《水文研究》2013,27(22):3240-3253

Exchange of groundwater and lake water with typically quite different chemical composition is an important driver for biogeochemical processes at the groundwater‐lake interface, which can affect the water quality of lakes. This is of particular relevance in mine lakes where anoxic and slightly acidic groundwater mixes with oxic and acidic lake water (pH < 3). To identify links between groundwater‐lake exchange rates and acid neutralization processes in the sediments, exchange rates were quantified and related to pore‐water pH, sulfate and iron concentrations as well as sulfate reduction rates within the sediment. Seepage rates measured with seepage meters (?2.5 to 5.8 L m^‐2 d^‐1) were in reasonable agreement with rates inverted from modeled chloride profiles (?1.8 to 8.1 L m^‐2 d^‐1). Large‐scale exchange patterns were defined by the (hydro)geologic setting but superimposed by smaller scale variations caused by variability in sediment texture. Sites characterized by groundwater upwelling (flow into the lake) and sites where flow alternated between upwelling and downwelling were identified. Observed chloride profiles at the alternating sites reflected the transient flow regime. Seepage direction, as well as seepage rate, were found to influence pH, sulfate and iron profiles and the associated sulfate reduction rates. Under alternating conditions proton‐consuming processes, for example, sulfate reduction, were slowed. In the uppermost layer of the sediment (max. 5 cm), sulfate reduction rates were significantly higher at upwelling (>330 nmol g^‐1 d^‐1) compared to alternating sites (<220 nmol g^‐1 d^‐1). Although differences in sulfate reduction rates could not be explained solely by different flux rates, they were clearly related to the prevailing groundwater‐lake exchange patterns and the associated pH conditions. Our findings strongly suggest that groundwater‐lake exchange has significant effects on the biogeochemical processes that are coupled to sulfate reduction such as acidity retention and precipitation of iron sulfides. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Private rights,public benefits: Industry-driven seabed protection     

Jeremy Helson  Stefan Leslie  George Clement  Richard Wells  Ray Wood 《Marine Policy》2010

New Zealand has a large exclusive economic zone (EEZ) that contains a variety of marine habitats and commercially-important species. The commercial fishing industry operating within New Zealand's EEZ is of significant value to the economy and fisheries resources are managed through the extensive use of Individual Transferable Quotas (ITQs). One of the benefits of ITQs has been to better align some of the private incentives of quota owners with the public interest. These incentives contributed to an initiative proposed by the fishing industry to close large areas of New Zealand's EEZ to protect the seabed from trawling. These closed areas are termed benthic protection areas (BPAs) and protect the benthic biodiversity of about 1.1 million square kilometres of seabed—approximately 30% of New Zealand's EEZ. A significant proportion of New Zealand's known seamounts and active hydrothermal vents are protected by these closed areas. We describe and discuss the criteria used to select BPAs and some of the criticism of this marine protection initiative. We argue that the assignment of strong property rights in fishing resources was an important precondition to an industry initiative that has a significant public benefit. Where private and public interests are well aligned, government can adopt an enabling and facilitation role, ceding direct control of processes in order to get the results the align with the public interest.  相似文献   

The impact of uncertain emission trading markets on interactive resource planning processes and international emission trading experiments   总被引：1，自引：1，他引：0  

Stefan Pickl  Erik Kropat  Heiko Hahn 《Climatic change》2010,103(1-2):327-338

Interactive resource planning is an increasingly important aspect of emission trading markets. The conferences of Rio de Janeiro, 1992, and Kyoto, 1997, originally focusing on environmental protection at both macro- and micro-economic levels, called for new economic instruments of this kind. An important economic tool in this area is Joint Implementation (JI), defined in Article 6 of the Kyoto Protocol. Sustainable development can be guaranteed only if JI is embedded in optimal energy management. In this contribution we describe and evaluate one international procedure within uncertain markets which helps to establish optimal energy management and interactive resource planning processes within uncertain emission trading markets.  相似文献   

North Atlantic climate impact on early late‐glacial climate oscillations in the south‐eastern Alps inferred from a multi‐proxy lake sediment record     

Roland Schmidt  Kaarina Weckström  Stefan Lauterbach  Richard Tessadri  Kerstin Huber 《第四纪科学杂志》2012,27(1):40-50

High‐resolution multi‐proxy analyses of a sediment core section from Lake Jeserzersee (Saissersee) in the piedmont lobe of the Würmian Drau glacier (Carinthia, Austria) reveal pronounced climatic oscillations during the early late glacial (ca. 18.5–16.0k cal a BP). Diatom‐inferred epilimnetic summer water temperatures show a close correspondence with temperature reconstructions from the adjacent Lake Längsee record and, on a hemispheric scale, with fluctuations of ice‐rafted debris in the North Atlantic. This suggests that North Atlantic climate triggered summer climate variability in the Alps during the early late glacial. The expansion of pine (mainly dwarf pine) between ca. 18.5 and 18.1k cal a BP indicates warming during the so‐called ‘Längsee oscillation’. The subsequent stepwise climate deterioration between ca. 18.1 and 17.6k cal a BP culminated in a tripartite cold period between ca. 17.6 and 16.9k cal a BP with diatom‐inferred summer water temperatures 8.5–10 °C below modern values and a shift from wet to dry conditions. This period probably coincides with a major Alpine glacier advance termed the Gschnitz stadial. A warmer interval between ca. 16.9 and 16.4k cal a BP separates this cold phase from a second, shorter and less pronounced cold phase between ca. 16.4 and 16.0k cal a BP, which is thought to correlate with the Clavadel/Senders glacier advance in the Alps. The following temperature increase, coupled with wet (probably snow‐rich) conditions, caused the expansion of birch during the transition period to the late glacial interstadial. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Multiple Forward Scattering of Surface Waves: Comparison With an Exact Solution and Born Single-Scattering Methods   总被引：2，自引：0，他引：2  

Wolfgang Friederich  Erhard Wielandt  Stefan Stange 《Geophysical Journal International》1993,112(2):264-275

  相似文献   

How does landfill leachate affect the chemical processes in a lake system downgradient from a landfill site?     

Thomas Striebel  Wolfgang Schäfer  Stefan Peiffer 《Aquatic Sciences - Research Across Boundaries》1991,53(4):346-366

A field study on the geochemical properties of a chemically-stressed limnic environment was performed in Lake Silbersee, which receives leachate water of high inorganic loading from an upgradient landfill site. The highly concentrated sulfate ion in groundwater, when entering the pore water system of the lake, gives rise to an intensive microbial sulfate reduction. A diagenetic approach was used to explain the existence of a marine-like aqueous system within a geologically slightly acidic aquifer, consisting of a well-buffered lake water and an alkalinity producing, excess sulphide containing sediment pore water system.  相似文献   

Book reviews     

Yukio Fujinawa  A. V. Koloskov  Gerardo G. Tango  Lech Stefaníak  Douglas R. Schmitt  Kei Katsumata  Vernon F. Cormier  Wladislaw Lyatsky  Krzysztof Haman  P. Vincent  Konrad Bajer  Henryk Piwkowski 《Pure and Applied Geophysics》1991,136(2-3):343-367

  相似文献   

Hyperfine interactions and spin transfer between Cr3+ and Al3+ in a synthetic single crystal of Mg2SiO4. A theoretical approach to the interpretation of EPR data     

S. Nagel  H. Rager 《Physics and Chemistry of Minerals》1985,12(5):291-299

The occurrence of Cr-Al pairs in Mg₂SiO₄ has been detected by EPR spectroscopy. In the case where Cr³⁺ replaces Mg at the M2 position three different neighboring Si sites may be substituted by Al³⁺, which should yield different superhyperfine interactions. A new spectrum is presented which shows the presence of two of these possible pair configurations. An assignment of the spectral features to a specific Cr-Al pair with Cr at M2 from the experimental data alone was not possible, therefore, MSX _α cluster calculations have been performed from which the differences in the superhyperfine interaction for the various pair configurations could be obtained. Best agreement with the data of the Cr³⁺(M2)-Al pair exhibiting the most intense group of lines in the EPR spectrum was obtained for the situation where Al³⁺ is at the Si position with the shortest distance to M2. The second observed Cr³⁺(M2)-Al pair, which is significantly weaker in intensity, could not yet be assigned.  相似文献   

Samarium-neodymium data on two late Proterozoic ophiolites of Saudi Arabia and implications for crustal and mantle evolution     

Stefan Claesson  John S. Pallister  Mitsunobu Tatsumoto 《Contributions to Mineralogy and Petrology》1984,85(3):244-252

Whole-rock and mineral samples from the Jabal al Wask and Jabal Ess ophiolites, northwestern Saudi Arabia, yield Sm-Nd isochron ages of 743+24 Ma and 782±38 Ma, respectively. These formation ages, which provide maximum limits for possible obduction ages, are in broad but not precise agreement with the previously known geologic history of the Arabian Shield. They indicate that the ophiolitic rocks are roughly coeval with nearby volcanic and plutonic rocks, supporting a back-arc origin for the two ophiolites. We suggest that the Jabal al Wask and Jabal Ess ophiolites were parts of the same northeast-southwest trending ophiolite belt, now offset along the Najd fault system. Initial _Nd values range from +6.6 to+ 7.6, indicating derivation from a mantle source that has been LIL-depleted for at least 2 Ga. Reported _Nd values from the Arabian Shield that are lower than this suggest the presence of older, reworked continental crust.  相似文献   

Pattern-Recognition-Verfahren in der Umweltanalytik und Ökotoxikologie: Methodische Grundlagen     

D. Feiler  M. Nagel  E. Stottmeister  R. Koch 《洁净——土壤、空气、水》1986,14(4):335-346

Modern methods of analyses of environment yield multivariate data sets of measured objects which are used as the basis of the evaluation and interpretation of substances, differentiated effects, but also of samples or processes. The integrated evaluation and assessment of such multivariate data requires the application of mathematical-statistical methods, the method of pattern recognition being particularly suitable. Pattern recognition program systems constitute a compilation of different methods, as e.g. the multivariate linear regression, classification methods (discriminant analysis, multivariate variance analysis), cluster algorithms, multidimensional scaling, factorial analysis. A few possibilities of such pattern comparisons and identifications are represented by the example of gas chromatography and of the structure/effect analysis for the mutagenity to be expected of 117 substances.  相似文献